Prédiction de la solubilité des corps gras dans le CO2 supercritique

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Date

2018

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Université constantine 3 Salah boubnider, Faculté génie des procédés

Abstract

Abstract: The objective of this work is the modeling of equilibrium between phases at high pressure using the equations of state for various binary-systems. Calculations were carried out by using 5 cubic equations of state EOS (VDW, RK, RKS, PR, and PT) combined with 2 mixing ruler MR (VW, P-R). The value of the saturated vapor pressure was optimized by software MATLAB 2017, in order to obtain a correct representation of the diagrams: Solubility of the fatty acids and Triglycerides in supercritical CO2 - Pressure. The results got in this work agree with the: experimental data of the literature, the EOS with combination the rule of mixture of VW seems most adequate in this work.

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Supercritical fluid, atty-acid, Equation of state, mixing role, Method of Joback, MATLAB 2017

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